Crystal structure and catalytic activity of tetrakis(μ2-ethyl 2,6-di-tert-butyl-4-methylphenyl phosphato-κ2O:O′)bis(ethyl 2,6-di-tert-butyl-4-methylphenyl phosphato-κ2O,O′)dilutetium n-heptane disolvate

Crystal structure and catalytic activity of tetrakis(μ2-ethyl 2,6-di-tert-butyl-4-methylphenyl phosphato-κ2O:O′)bis(ethyl 2,6-di-tert-butyl-4-methylphenyl phosphato-κ2O,O′)dilutetium n-heptane disolvate

The title complex, [Lu2(C17H28O4P)6]·2C7H16, was formed in the reaction between potassium 2,6-di-tert-butyl-4-methylphenyl ethyl phosphate, [K(2,6-tBu2-4-MeC6H2-O)(EtO)PO2], and LuCl3(H2O)6 in water, followed by vacuum drying and recrystallization from heptane. Its crystal structure has triclinic (P...

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Bibliographic Details
Main Authors: Mikhail E. Minyaev, Alexander N. Tavtorkin, Sof'ya A. Korchagina, Ilya E. Nifant'ev, Andrei V. Churakov
Format: Article
Language:English
Published: International Union of Crystallography 2018-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
lutetium
organophosphate
binuclear complex
coordination compound
acrylonitrile polymerization
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018004565

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http://scripts.iucr.org/cgi-bin/paper?S2056989018004565

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