Synthesis of a [6]rotaxane with singly threaded γ-cyclodextrins as a single stereoisomer

A series of hetero [4]-, [5]- and [6]rotaxanes containing both cucurbit[6]uril (CB[6]) and γ-cyclodextrin (γ-CD) as the macrocyclic components have been synthesized via a threading-followed-by-stoppering approach. Due to the orthogonal binding of CB[6] to ammonium and γ-CD to biphenylene/tetra(ethyl...

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Bibliographic Details
Main Authors: Jason Yin Hei Man, Ho Yu Au-Yeung
Format: Article
Language:English
Published: Beilstein-Institut 2019-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.15.177