Synthesis of a [6]rotaxane with singly threaded γ-cyclodextrins as a single stereoisomer
A series of hetero [4]-, [5]- and [6]rotaxanes containing both cucurbit[6]uril (CB[6]) and γ-cyclodextrin (γ-CD) as the macrocyclic components have been synthesized via a threading-followed-by-stoppering approach. Due to the orthogonal binding of CB[6] to ammonium and γ-CD to biphenylene/tetra(ethyl...
Main Authors: | , |
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Format: | Article |
Language: | English |
Published: |
Beilstein-Institut
2019-08-01
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Series: | Beilstein Journal of Organic Chemistry |
Subjects: | |
Online Access: | https://doi.org/10.3762/bjoc.15.177 |