Reactivity of a-Oxophosphonium Ylides: A Contribution to the Mechanistics

Reactivity of a-Oxophosphonium Ylides: A Contribution to the Mechanistics

Ylides 1f and 1g react with chlorine, with bromine and with N-chlorosuccinimide in the presence of a range of nucleophiles. The 2,3-disubstitutedbutenedioates obtained in this way allow us to gather more information about the mechanism involved. Ylide 1c was also studied showing similar reactivity a...

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Bibliographic Details
Main Authors: Ana M. O. M. P. Taborda, Sara M. S. Carrapato, António M. d’A. Rocha Gonsalves, Teresa M.V.D. Pinho e Melo
Format: Article
Language:English
Published: MDPI AG 1999-07-01
Series:Molecules
Subjects:
phosphorus ylides
tetrasubstituted alkenes
Online Access:http://www.mdpi.com/1420-3049/4/7/219/

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http://www.mdpi.com/1420-3049/4/7/219/

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