catena-Poly[tetrasodium [[cis-dioxido-trans-bis(sulfato-κO)molybdate(VI)]-μ-sulfato-κ2O:O′]]

Single crystals of the title compound, {Na4[MoVIO2(SO4)3]}n, were grown from a melt of MoO3 and Na2SO4 in Na2S2O7. In contrast to the structure of the isoformular K compound, K4[MoVIO2(SO4)3], with its monomeric anion, this sodium analogue contains a polymeric anion of the type {[MoVIO2(SO4)2-&#...

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Bibliographic Details
Main Authors: Susan J. Cline Schäffer, Rolf W. Berg
Format: Article
Language:English
Published: International Union of Crystallography 2008-11-01
Series:Acta Crystallographica Section E
Online Access:http://scripts.iucr.org/cgi-bin/paper?S1600536808030328