Towards Iron(II) Complexes with Octahedral Geometry: Synthesis, Structure and Photophysical Properties

Towards Iron(II) Complexes with Octahedral Geometry: Synthesis, Structure and Photophysical Properties

The control of ligand-field splitting in iron (II) complexes is critical to slow down the metal-to-ligand charge transfer (MLCT)-excited states deactivation pathways. The gap between the metal-centered states is maximal when the coordination sphere of the complex approaches an ideal octahedral geome...

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Bibliographic Details
Main Authors: Mohamed Darari, Antonio Francés-Monerris, Bogdan Marekha, Abdelatif Doudouh, Emmanuel Wenger, Antonio Monari, Stefan Haacke, Philippe C. Gros
Format: Article
Language:English
Published: MDPI AG 2020-12-01
Series:Molecules
Subjects:
iron (II) complexes
octahedral geometry
excited states dynamics
density functional theory
time-resolved spectroscopy
Online Access:https://www.mdpi.com/1420-3049/25/24/5991

Internet

https://www.mdpi.com/1420-3049/25/24/5991

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