Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity

Cu42Ge24Na4—A Giant Trimetallic Sesquioxane Cage: Synthesis, Structure, and Catalytic Activity

Unprecedented germanium-based sesquioxane exhibits an extremely high nuclearity (Cu42Ge24Na4) and unusual encapsulation features. The compound demonstrated a high catalytic activity in the oxidative amidation of alcohols, with cost-effective catalyst loading down to 400 ppm of copper, and in the oxi...

Full description

Bibliographic Details
Main Authors: Alena N. Kulakova, Alexey N. Bilyachenko, Victor N. Khrustalev, Yan V. Zubavichus, Pavel V. Dorovatovskii, Lidia S. Shul’pina, Xavier Bantreil, Frédéric Lamaty, Elena S. Shubina, Mikhail M. Levitsky, Georgiy B. Shul’pin
Format: Article
Language:English
Published: MDPI AG 2018-10-01
Series:Catalysts
Subjects:
alkanes
amides
hydrogen peroxide
multinuclear complexes
iron complexes
metallasiloxanes
Online Access:http://www.mdpi.com/2073-4344/8/10/484

Internet

http://www.mdpi.com/2073-4344/8/10/484

Similar Items