Synthesis of functionalized diazocines for application as building blocks in photo- and mechanoresponsive materials

Seven symmetrically 3,3’-substituted diazocines were synthesized. Functional groups include alcohol, azide, amine and vinyl groups, which are suitable for polymer synthesis. Upon irradiation at 385 and 530 nm the diazocines perform a reversible, pincer-type movement switching the 3,3’-distance betwe...

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Bibliographic Details
Main Authors: Widukind Moormann, Daniel Langbehn, Rainer Herges
Format: Article
Language:English
Published: Beilstein-Institut 2019-03-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.15.68