Bis{N′-[3-(4-nitrophenyl)-1-phenylprop-2-en-1-ylidene]-N-phenylcarbamimidothioato}zinc(II): crystal structure, Hirshfeld surface analysis and computational study

Bis{N′-[3-(4-nitrophenyl)-1-phenylprop-2-en-1-ylidene]-N-phenylcarbamimidothioato}zinc(II): crystal structure, Hirshfeld surface analysis and computational study

The title zinc bis(thiosemicarbazone) complex, [Zn(C22H17N4O2S)2], comprises two N,S-donor anions, leading to a distorted tetrahedral N2S2 donor set. The resultant five-membered chelate rings are nearly planar and form a dihedral angle of 73.28 (3)°. The configurations about the endocyclic- and exoc...

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Bibliographic Details
Main Authors: Ming Yueh Tan, Huey Chong Kwong, Karen A. Crouse, Thahira B. S. A. Ravoof, Edward R. T. Tiekink
Format: Article
Language:English
Published: International Union of Crystallography 2021-08-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
zinc
schiff base
thiosemicarbazone
hydrogen bonding
hirshfeld surface analysis
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989021007398

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http://scripts.iucr.org/cgi-bin/paper?S2056989021007398

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