Catalytic Enantioselective Addition of Organozirconium Reagents to Aldehydes

Catalytic Enantioselective Addition of Organozirconium Reagents to Aldehydes

A catalytic enantioselective addition reaction of alkylzirconium species to aromatic aldehydes is reported. The reaction, facilitated by a chiral nonracemic diol ligand complex with Ti(OiPr)4, proceeds under mild and convenient conditions, and no premade organometallic reagents are required since th...

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Bibliographic Details
Main Authors: Ricard Solà, Marcos Veguillas, María José González-Soria, Nicholas Carter, M. Angeles Fernández-Ibáñez, Beatriz Maciá
Format: Article
Language:English
Published: MDPI AG 2018-04-01
Series:Molecules
Subjects:
alkenes
asymmetric catalysis
titanium
addition to aldehydes
Schwartz reagent
Online Access:http://www.mdpi.com/1420-3049/23/4/961

Internet

http://www.mdpi.com/1420-3049/23/4/961

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