Synthesis of tetrahydrokhusitone: Annulation of the cyclohexane ring by free radical and carbanionic sequence of reactions

The synthesis of norcadinane sesquiterpene tetrahydrokhusitone 1 has been achieved by a new method for annulation of cyclohexane ring involving a sequence of free radical δ-alkylation of the non-activated carbon atom and intramolecular carbanionic alkylation. (–)-Menthol was used as the starting com...

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Bibliographic Details
Main Authors: Petrović Goran, Čeković Živorad
Format: Article
Language:English
Published: Serbian Chemical Society 2003-01-01
Series:Journal of the Serbian Chemical Society
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/0352-5139/2003/0352-51390305313P.pdf