The First Chelate-Free Crystal Structure of a Silicide Transition Metal Complex [K0.28Rb7.72Si9Ni(CO)2]2·16NH3
Single-crystals X-ray structure analysis of very thermally labile and moisture sensitive ammoniate crystals of [K0.28Rb7.72Si9Ni(CO)2]2·16NH3 show the presence of the very rarely observed nickel-silicide complex [{Ni(CO)2}2(µ-Si9)2]8−, which was up to now only known in the 18-crown-6 involving solid...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2015-06-01
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| Series: | Crystals |
| Subjects: | |
| Online Access: | http://www.mdpi.com/2073-4352/5/3/275 |