Synthesis, Structure and Bonding Analysis of the Zwitterionic PPP-Pincer Complex (6-Ph<sub>2</sub>P-Ace-5-)<sub>2</sub>P(O)AuCl<sub>2</sub>

Synthesis, Structure and Bonding Analysis of the Zwitterionic PPP-Pincer Complex (6-Ph<sub>2</sub>P-Ace-5-)<sub>2</sub>P(O)AuCl<sub>2</sub>

The reaction of (6-Ph<sub>2</sub>P-Ace-5-)<sub>2</sub>P(O)H with (tht)AuCl<sub>3</sub> proceeds via elimination of tetrahydrothiophene (tht) and HCl, providing the zwitterionic PPP-pincer complex (6-Ph<sub>2</sub>P-Ace-5-)<sub>2</sub>P(O)Au...

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Bibliographic Details
Main Authors: Daniel Duvinage, Enno Lork, Simon Grabowsky, Stefan Mebs, Jens Beckmann
Format: Article
Language:English
Published: MDPI AG 2020-07-01
Series:Crystals
Subjects:
Pincer ligands
secondary phosphine oxide
gold complex
real-space bonding indicators
Online Access:https://www.mdpi.com/2073-4352/10/7/564

Internet

https://www.mdpi.com/2073-4352/10/7/564

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