Qualitative Analysis of the Helical Electronic Energy of Inherently Chiral Calix[4]arenes: An Approach to Effectively Assign Their Absolute Configuration

Qualitative Analysis of the Helical Electronic Energy of Inherently Chiral Calix[4]arenes: An Approach to Effectively Assign Their Absolute Configuration

For all microhelices on aromatic rings of inherently chiral calix[4]arene, an expression was derived from one approximation and one hypothesis on the basis of the electron-on-a-helix model of Tinoco and Woody as follows: 1/E = μ (H − K Δα2) , where μ = 1 for the right-handed microhelix and μ = −1 f...

Full description

Bibliographic Details
Main Authors: Shuang Zheng, Ming-Liang Chang, Jing Zhou, Jing-Wei Fu, Qing-Wei Zhang, Shao-Yong Li, Wei Qiao, Jun-Min Liu
Format: Article
Language:English
Published: MDPI AG 2014-06-01
Series:International Journal of Molecular Sciences
Subjects:
inherently chiral
calix[4]arene
helix theory
absolute configuration
Online Access:http://www.mdpi.com/1422-0067/15/6/9844

Internet

http://www.mdpi.com/1422-0067/15/6/9844

Similar Items