Planar chiral 2-(trifluoromethyl)quinoline-fused ferrocenes via palladium(0)-catalyzed C-H functionalization of trifluoroacetimidoyl chlorides

Planar chiral 2-(trifluoromethyl)quinoline-fused ferrocenes via palladium(0)-catalyzed C-H functionalization of trifluoroacetimidoyl chlorides

Catalytic enantioselective synthesis of planar chiral 2-(trifluoromethyl)quinoline-fused ferrocenes has been achieved through Pd(0)-catalyzed C-H functionalization with trifluoroacetimidoyl chlorides as electrophilics. With commercially available ligand and palladium precursor, the reaction proceeds...

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Bibliographic Details
Main Authors: An-An Zhang, Chao Chen, Yushen Gao, Mingyang Mo, Ren-Zeng Shen, Yu-Heng Zhang, Naoki Ishida, Masahiro Murakami, Lantao Liu
Format: Article
Language:English
Published: KeAi Communications Co. Ltd. 2021-08-01
Series:Green Synthesis and Catalysis
Subjects:
Planar-chiral ferrocenes
Palladium
C-H functionalization
2-(Trifluoromethyl)quinolines
Trifluoroacetimidoyl chlorides
Online Access:http://www.sciencedirect.com/science/article/pii/S2666554921000545

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http://www.sciencedirect.com/science/article/pii/S2666554921000545

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