Crystal structure of bis(1,10-phenanthroline-κ2N,N′)(1,3-thiazole-2-thiolato-κ2S2,N)nickel(II) hexafluoridophosphate 1,4-dioxane sesquisolvate

Crystal structure of bis(1,10-phenanthroline-κ2N,N′)(1,3-thiazole-2-thiolato-κ2S2,N)nickel(II) hexafluoridophosphate 1,4-dioxane sesquisolvate

The title salt, [Ni(C3H2NS2)(C12H8N2)2]PF6·1.5C4H8O2, was the unexpected product on making an attempt to prepare an [Ni(2-mercaptothiazolate)(1,10-phenanthroline)]+ complex by reaction of [NiCl2(1,10-phenanthroline)] with 2-mercaptothiazolate. In the resulting complex, the 2-mercaptothiazolate anion...

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Bibliographic Details
Main Authors: Keisuke Kai, Tomohiko Hamaguchi, Isao Ando
Format: Article
Language:English
Published: International Union of Crystallography 2017-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
2-mercaptothiazolate
π–π stacking
hydrogen bonding
nickel(II) complex
Online Access:http://scripts.iucr.org/cgi-bin/paper?S205698901700456X

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http://scripts.iucr.org/cgi-bin/paper?S205698901700456X

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