Spontaneous enantiomorphism in poly-phased alkaline salts of tris(oxalato)ferrate(III): crystal structure of cubic NaRb5[Fe(C2O4)3]2

Spontaneous enantiomorphism in poly-phased alkaline salts of tris(oxalato)ferrate(III): crystal structure of cubic NaRb5[Fe(C2O4)3]2

We show here that the phenomenon of spontaneous resolution of enantiomers occurs during the crystallization of the sodium and rubidium double salts of the transition metal complex tris(oxalato)ferrate(III), namely sodium pentarubidium bis[tris(oxalato)ferrate(III)], NaRb5[Fe(C2O4)3]2. One enantiomer...

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Bibliographic Details
Main Authors: O. E. Piro, G. A. Echeverría, E. J. Baran
Format: Article
Language:English
Published: International Union of Crystallography 2018-07-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
absolute crystal structures
spontaneous resolution of enantiomorphs
sodium and rubidium salt of tris(oxalato)ferrate(III)
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989018008022

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http://scripts.iucr.org/cgi-bin/paper?S2056989018008022

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