Synthesis and structure of trans-bis(1,4-dimesityl-3-methyl-1,2,3-triazol-5-ylidene)palladium(II) dichloride and diacetate. Suzuki–Miyaura coupling of polybromoarenes with high catalytic turnover efficiencies

Synthesis and structure of trans-bis(1,4-dimesityl-3-methyl-1,2,3-triazol-5-ylidene)palladium(II) dichloride and diacetate. Suzuki–Miyaura coupling of polybromoarenes with high catalytic turnover efficiencies

trans-Bis(1,4-dimesityl-3-methyl-1,2,3-triazol-5-ylidene)palladium(II) dichloride has been shown to be an excellent catalyst for the multiple Suzuki–Miyaura coupling reactions of polybromoarenes to the corresponding fully substituted polyarylarenes. The reactions proceeded in excellent yields and wi...

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Bibliographic Details
Main Authors: Jeelani Basha Shaik, Venkatachalam Ramkumar, Babu Varghese, Sethuraman Sankararaman
Format: Article
Language:English
Published: Beilstein-Institut 2013-04-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
C–C coupling
N-heterocyclic carbene
palladium
Suzuki–Miyaura coupling
1,2,3-triazolylidene
Online Access:https://doi.org/10.3762/bjoc.9.79

Internet

https://doi.org/10.3762/bjoc.9.79

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