Metathesis Polymerization Reactions Induced by the Bimetallic Complex (Ph4P)2[W2(μ-Br)3Br6]

Metathesis Polymerization Reactions Induced by the Bimetallic Complex (Ph4P)2[W2(μ-Br)3Br6]

The reactivity of the bimetallic complex (Ph4P)2[W2(μ-Br)3Br6] ({W 2.5 W}7+, a′2e3) towards ring opening metathesis polymerization (ROMP) of norbornene (NBE) and some of its derivatives, as well as the mechanistically related metathesis polymerization of phenylacetylene (PA), is presented. Our resul...

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Bibliographic Details
Main Authors: Despoina Chriti, Alexios Grigoropoulos, Grigorios Raptopoulos, Georgios Charalambidis, Vasilis Nikolaou, Athanassios G. Coutsolelos, Marinos Pitsikalis, Konstantinos Mertis, Patrina Paraskevopoulou
Format: Article
Language:English
Published: MDPI AG 2015-12-01
Series:Polymers
Subjects:
metathesis
ROMP
metal-metal bonds
tungsten
Online Access:http://www.mdpi.com/2073-4360/7/12/1536

Internet

http://www.mdpi.com/2073-4360/7/12/1536

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