Catalytic Performance of Fe(II)-Scorpionate Complexes towards Cyclohexane Oxidation in Organic, Ionic Liquid and/or Supercritical CO2 Media: A Comparative Study

Catalytic Performance of Fe(II)-Scorpionate Complexes towards Cyclohexane Oxidation in Organic, Ionic Liquid and/or Supercritical CO2 Media: A Comparative Study

The catalytic activity of the iron(II) C-scorpionate complexes [FeCl2{HC(pz)3}] 1 (pz = pyrazol-1-yl) and [FeCl2{HOCH2C(pz)3}] 2, and of their precursor FeCl2·2H2O 3, towards cyclohexane oxidation with tert-butyl hydroperoxide was evaluated and compared in different media: acetonitrile, ionic liquid...

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Bibliographic Details
Main Authors: Ana P. C. Ribeiro, Luísa M. D. R. S. Martins, Elisabete C. B. A. Alegria, Inês A. S. Matias, Tiago A. G. Duarte, Armando J. L. Pombeiro
Format: Article
Language:English
Published: MDPI AG 2017-08-01
Series:Catalysts
Subjects:
ionic liquid
supercritical carbon dioxide
cyclohexane
oxidation
C-scorpionate
catalyst
Online Access:https://www.mdpi.com/2073-4344/7/8/230

Internet

https://www.mdpi.com/2073-4344/7/8/230

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