Synthesis of PAN with adjustable molecular weight and low polydispersity index (PDI) value via reverse atom transfer radical polymerization

Synthesis of PAN with adjustable molecular weight and low polydispersity index (PDI) value via reverse atom transfer radical polymerization

The reverse atom transfer radical polymerization (RATRP) of acrylonitrile (AN) was carried out in N, N-dimethylformamide (DMF) with AIBN as initiator, FeCl3•6H2O/triphenylphosphine (PPh3) and FeCl3•6H2O/pentamethyldle-thylenetrlamlne (PMDETA) as catalytic systems, respectively. Effect of reaction ti...

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Bibliographic Details
Main Authors: Shuang Li, Yazhen Wang, Liqun Ma, Xueze Zhang, Shaobo Dong, Li Liu, Xilai Zhou, Chenglong Wang, Zhen Shi
Format: Article
Language:English
Published: Taylor & Francis Group 2019-01-01
Series:Designed Monomers and Polymers
Subjects:
ratrp
acrylonitrile
molecular weight
polydispersity index
Online Access:http://dx.doi.org/10.1080/15685551.2019.1678557

Internet

http://dx.doi.org/10.1080/15685551.2019.1678557

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