Conversion of Oximes to Carbonyl Compounds by Triscetylpyridinium Tetrakis(oxodiperoxotungsto) Phosphate (PCWP)-mediated Oxidation with Hydrogen Peroxide

Conversion of Oximes to Carbonyl Compounds by Triscetylpyridinium Tetrakis(oxodiperoxotungsto) Phosphate (PCWP)-mediated Oxidation with Hydrogen Peroxide

Aromatic and aliphatic oximes have been deoximated in chloroform-water to the corresponding aldehydes with dilute hydrogen peroxide and triscetylpyridinium tetrakis (oxodiperoxotungsto) phosphate as catalyst. The presence of dipolarophiles in the reaction mixtures allows a competitive reaction that...

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Bibliographic Details
Main Authors: Rosa M. Toscano, Gaetano Tomaselli, Antonio Rescifina, Ugo Chiacchio, Francesco P. Ballistreri
Format: Article
Language:English
Published: MDPI AG 2008-06-01
Series:Molecules
Subjects:
Oxidation of oximes
oxodiperoxotungsto complex
1
3-dipolar cycloaddition
nitrile oxides
aldehydes.
Online Access:http://www.mdpi.com/1420-3049/13/6/1230/

Internet

http://www.mdpi.com/1420-3049/13/6/1230/

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