Highly substituted benzannulated cyclooctanol derivatives by samarium diiodide-induced cyclizations

A series of γ-oxo esters suitably substituted with various styrene subunits was subjected to samarium diiodide-induced 8-endo-trig cyclizations. Efficacy, regioselectivity and stereoselectivity of these reactions via samarium ketyls strongly depend on the substitution pattern of the attacked alkene...

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Bibliographic Details
Main Authors: Jakub Saadi, Irene Brüdgam, Hans-Ulrich Reissig
Format: Article
Language:English
Published: Beilstein-Institut 2010-12-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
Online Access:https://doi.org/10.3762/bjoc.6.141