Short X···N Halogen Bonds With Hexamethylenetetraamine as the Acceptor

Short X···N Halogen Bonds With Hexamethylenetetraamine as the Acceptor

Hexamethylenetetramine (HMTA) and N-haloimides form two types of short (imide)X···N and X–X···N (X = Br, I) halogen bonds. Nucleophilic substitution or ligand-exchange reaction on the peripheral X of X–X···N with the chloride of N-chlorosuccinimide lead to Cl–X···N halogen-bonded complexes. The 1:1...

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Bibliographic Details
Main Authors: Goulielmina Anyfanti, Antonio Bauzá, Lorenzo Gentiluomo, João Rodrigues, Gustavo Portalone, Antonio Frontera, Kari Rissanen, Rakesh Puttreddy
Format: Article
Language:English
Published: Frontiers Media S.A. 2021-04-01
Series:Frontiers in Chemistry
Subjects:
halogen bond
hexamethylenetetraamine
HMTA
N-haloimide
dihalogen
interhalogen
Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2021.623595/full

Internet

https://www.frontiersin.org/articles/10.3389/fchem.2021.623595/full

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