Highly Efficient Bifunctional Amide Functionalized Zn and Cd Metal Organic Frameworks for One-Pot Cascade Deacetalization–Knoevenagel Reactions

Highly Efficient Bifunctional Amide Functionalized Zn and Cd Metal Organic Frameworks for One-Pot Cascade Deacetalization–Knoevenagel Reactions

A pyridine-based amide functionalized tetracarboxylic acid, 5,5′-(pyridine-2, 6-dicarbonyl)bis(azanediyl)}diisophthalic acid (H4L), was synthesized and its coordination chemistry toward zinc(II) and cadmium(II) ions was studied. The reactions of H4L with Zn(NO3)2.6H2O and Cd(NO3)2.4H2O led to its fu...

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Bibliographic Details
Main Authors: Anirban Karmakar, Anup Paul, Guilherme M. D. M. Rúbio, Mohamed M. A. Soliman, M. Fátima C. Guedes da Silva, Armando J. L. Pombeiro
Format: Article
Language:English
Published: Frontiers Media S.A. 2019-10-01
Series:Frontiers in Chemistry
Subjects:
metal organic framework (MOF)
crystal structure analysis
heterogeneous catalysis
cascade reaction
amide
Online Access:https://www.frontiersin.org/article/10.3389/fchem.2019.00699/full

Internet

https://www.frontiersin.org/article/10.3389/fchem.2019.00699/full

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