Bisguanidinium dinuclear oxodiperoxomolybdosulfate ion pair-catalyzed enantioselective sulfoxidation
Peroxomolybdates can be used as catalysts, but to date have not been employed in catalytic asymmetric transformations. Here the authors report that peroxomolybdates with a chiral bisguanidinium salts are active catalysts for asymmetric sulfoxidation, and furthermore identify the catalytic species.
| Main Authors: | , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Nature Publishing Group
2016-11-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/ncomms13455 |