Helix-Sense-Selective Polymerization of Phenylacetylenes Having a Porphyrin and a Zinc-Porphyrin Group: One-Handed Helical Arrangement of Porphyrin Pendants
Newly synthesized two kinds of achiral phenylacetylenes having a free-base- or a zinc-porphyrin (<b>1</b> and <b>Zn1</b>, respectively) were polymerized by using a chiral rhodium catalyst system, Rh<sup>+</sup>(nbd)[(<i>η</i><sup>6</s...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2019-02-01
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| Series: | Polymers |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2073-4360/11/2/274 |