Consequences of the electronic tuning of latent ruthenium-based olefin metathesis catalysts on their reactivity

Consequences of the electronic tuning of latent ruthenium-based olefin metathesis catalysts on their reactivity

Two ruthenium olefin metathesis initiators featuring electronically modified quinoline-based chelating carbene ligands are introduced. Their reactivity in RCM and ROMP reactions was tested and the results were compared to those obtained with the parent unsubstituted compound. The studied complexes a...

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Bibliographic Details
Main Authors: Karolina Żukowska, Eva Pump, Aleksandra E. Pazio, Krzysztof Woźniak, Luigi Cavallo, Christian Slugovc
Format: Article
Language:English
Published: Beilstein-Institut 2015-08-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
DFT calculations
olefin metathesis
ring closing metathesis
ring-opening metathesis polymerisation
ruthenium
Online Access:https://doi.org/10.3762/bjoc.11.158

Internet

https://doi.org/10.3762/bjoc.11.158

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