Synthesis and Structural Characterization of a Series of One-Dimensional Heteronuclear Dirhodium-Silver Coordination Polymers

Synthesis and Structural Characterization of a Series of One-Dimensional Heteronuclear Dirhodium-Silver Coordination Polymers

Herein, we describe the preparation of heteronuclear dirhodium-silver complexes by reaction between molecular Rh(II)-Rh(II) compounds [Rh2(μ-O2CR)4L2] (R = Me, Ph (1), CH2OEt (2); L = solvent molecules) with paddlewheel structure and PPh4[Ag(CN)2]. One-dimensional coordination polymers of (PP...

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Bibliographic Details
Main Authors: Paula Cruz, Estefania Fernandez-Bartolome, Miguel Cortijo, Patricia Delgado-Martínez, Rodrigo González-Prieto, José L. Priego, M. Rosario Torres, Reyes Jiménez-Aparicio
Format: Article
Language:English
Published: MDPI AG 2019-01-01
Series:Polymers
Subjects:
dirhodium compounds
dicyano-argentate complexes
heteronuclear
one-dimensional
rhodium-silver chains
phenyl embrace
Online Access:http://www.mdpi.com/2073-4360/11/1/111

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http://www.mdpi.com/2073-4360/11/1/111

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