[Se(CH2C(O)CH3)3][B12F11NH3]: The first selenium cation with three β-ketone substituents

The reaction of [Se8][B12F11NH3]2 with acetone and subsequent crystallization from acetone/diethyl ether yielded the selenium cation [Se(CH2C(O)CH3)3]+ as a by-product, which is stabilized by the weakly coordinating undecafluorinated anion [B12F11NH3]−. While attempting to crystallize pure [Se8][B12...

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Bibliographic Details
Main Authors: Carsten Jenne, Marc C. Nierstenhöfer
Format: Article
Language:English
Published: International Union of Crystallography 2020-02-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989020000481