Polystyrene grafted onto high-cis-1,4 polybutadiene backbone via 'living' radical polymerization with 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) radical

Polystyrene grafted onto high-cis-1,4 polybutadiene backbone via 'living' radical polymerization with 2,2,6,6-tetramethylpiperidinyl-1-oxy (TEMPO) radical

A stable nitroxide radical (2,2,6,6-tetramethylpiperidinyl-1-oxy, TEMPO) was employed to a grafting polymerization of styrene onto the high-cis-1,4 polybutadiene (PB) rubber initiated by 1,1-bis(tert-butylperoxy)cyclohexane (DP275B). The influence of TEMPO/DP275B ratio on the reaction progress, mole...

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Bibliographic Details
Format: Article
Language:English
Published: Budapest University of Technology 2011-10-01
Series:eXPRESS Polymer Letters
Subjects:
Polymer composites
living radical polymerization
TEMPO
mechanical properties
fracture mechanism
Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0002484&mi=cd

Internet

http://www.expresspolymlett.com/letolt.php?file=EPL-0002484&mi=cd

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