Visible-light Promoted Atom Transfer Radical Addition−Elimination (ATRE) Reaction for the Synthesis of Fluoroalkylated Alkenes Using DMA as Electron-donor

Visible-light Promoted Atom Transfer Radical Addition−Elimination (ATRE) Reaction for the Synthesis of Fluoroalkylated Alkenes Using DMA as Electron-donor

Here, we describe a mild, catalyst-free and operationally-simple strategy for the direct fluoroalkylation of olefins driven by the photochemical activity of an electron donor−acceptor (EDA) complex between DMA and fluoroalkyl iodides. The significant advantages of this photochemical transf...

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Bibliographic Details
Main Authors: Wen-Wen Xu, Le Wang, Ting Mao, Jiwei Gu, Xiao-Fei Li, Chun-Yang He
Format: Article
Language:English
Published: MDPI AG 2020-01-01
Series:Molecules
Subjects:
fluoroalkyl iodides
eda
noncovalent interaction
fluoroalkylated alkenes
dma
Online Access:https://www.mdpi.com/1420-3049/25/3/508

Internet

https://www.mdpi.com/1420-3049/25/3/508

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