Iron-Catalyzed Cross-Coupling of <i>Bis</i>-(aryl)manganese Nucleophiles with Alkenyl Halides: Optimization and Mechanistic Investigations

Iron-Catalyzed Cross-Coupling of <i>Bis</i>-(aryl)manganese Nucleophiles with Alkenyl Halides: Optimization and Mechanistic Investigations

Various substituted <i>bis</i>-(aryl)manganese species were prepared from aryl bromides by one-pot insertion of magnesium turnings in the presence of LiCl and in situ trans-metalation with MnCl<sub>2</sub> in THF at &#8722;5 &#176;C within 2 h. These <i>bis</...

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Bibliographic Details
Main Authors: Lidie Rousseau, Alexandre Desaintjean, Paul Knochel, Guillaume Lefèvre
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Molecules
Subjects:
iron catalysis
cross-coupling
<i>bis</i>-(aryl)manganese
alkenyl halides
<i>ate</i> iron(ii) complex
Online Access:https://www.mdpi.com/1420-3049/25/3/723

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https://www.mdpi.com/1420-3049/25/3/723

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