Effect of para‐Substituents in Ethylene Copolymerizations with 1‐Decene, 1‐Dodecene, and with 2‐Methyl‐1‐Pentene Using Phenoxide Modified Half‐Titanocenes‐MAO Catalyst Systems

Effect of para‐Substituents in Ethylene Copolymerizations with 1‐Decene, 1‐Dodecene, and with 2‐Methyl‐1‐Pentene Using Phenoxide Modified Half‐Titanocenes‐MAO Catalyst Systems

Abstract Effect of para‐substituents in the ethylene (E) copolymerization with 1‐decene (DC), 1‐dodecene (DD), and with 2‐methyl‐1‐pentene (2M1P) using a series of Cp*TiCl2(O‐2,6‐iPr2‐4‐R‐C6H2) [R=H (1), tBu (2), Ph (3), CHPh2 (4), CPh3 (5), SiMe3 (6), SiEt3 (7), and newly prepared 4‐tBuC6H4 (8) and...

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Bibliographic Details
Main Authors: Suphitchaya Kitphaitun, Dr. Qing Yan, Prof. Dr. Kotohiro Nomura
Format: Article
Language:English
Published: Wiley-VCH 2021-09-01
Series:ChemistryOpen
Subjects:
ethylene copolymerization
half-titanocenes
homogeneous catalysis
ligand effects
titanium catalysts
Online Access:https://doi.org/10.1002/open.202100047

Internet

https://doi.org/10.1002/open.202100047

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