Unveiling the Different Chemical Reactivity of Diphenyl Nitrilimine and Phenyl Nitrile Oxide in [3+2] Cycloaddition Reactions with (R)-Carvone through the Molecular Electron Density Theory

Unveiling the Different Chemical Reactivity of Diphenyl Nitrilimine and Phenyl Nitrile Oxide in [3+2] Cycloaddition Reactions with (R)-Carvone through the Molecular Electron Density Theory

The [3+2] cycloaddition (32CA) reactions of diphenyl nitrilimine and phenyl nitrile oxide with (R)-carvone have been studied within the Molecular Electron Density Theory (MEDT). Electron localisation function (ELF) analysis of these three-atom-components (TACs) permits its characterisation as carben...

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Bibliographic Details
Main Authors: Mar Ríos-Gutiérrez, Luis R. Domingo, M’hamed Esseffar, Ali Oubella, My Youssef Ait Itto
Format: Article
Language:English
Published: MDPI AG 2020-02-01
Series:Molecules
Subjects:
[3+2] cycloadditions
nitrilimines
nitrile oxides
chemoselectivity
molecular electron density theory
molecular mechanisms
Online Access:https://www.mdpi.com/1420-3049/25/5/1085

Internet

https://www.mdpi.com/1420-3049/25/5/1085

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