Synthesis and structure of [Na(15-crown-5)][Ph2P(S)OB(C6F5)3] and [Na(15-crown-5)2][Ph2P(S)O···HO(S)PPh2]

Synthesis and structure of [Na(15-crown-5)][Ph2P(S)OB(C6F5)3] and [Na(15-crown-5)2][Ph2P(S)O···HO(S)PPh2]

The reaction of Ph2P(S)ONa with B(C6F5)3 in the presence of the crown ether 15-crown-5 provided the borate complex [Na(15-crown-5)][Ph2P(S)OB(C6F5)3] (1). In one occasion a few crystals of the hydrogen-bonded complex [Na(15-crown-5)2][Ph2P(S)O···HO(S)PPh2] (2) were obtained, which formed upon the ac...

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Bibliographic Details
Main Authors: Kather Ralf, Lork Enno, Raţ Ciprian-Ionuţ, Silvestru Cristian, Beckmann Jens
Format: Article
Language:English
Published: De Gruyter 2017-04-01
Series:Main Group Metal Chemistry
Subjects:
boron
hydrogen bonding
lewis acid
phosphinate
Online Access:https://doi.org/10.1515/mgmc-2017-0016

Internet

https://doi.org/10.1515/mgmc-2017-0016

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