Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide

The rational design of intercalation electrodes is largely confined to the optimization of redox chemistry of transition metals and oxygen. Here, the authors report the single anionic redox process in NaCrS2 where it is sulfur rather than chromium that works as the electrochemical active species.

Bibliographic Details
Main Authors: Zulipiya Shadike, Yong-Ning Zhou, Lan-Li Chen, Qu Wu, Ji-Li Yue, Nian Zhang, Xiao-Qing Yang, Lin Gu, Xiao-Song Liu, Si-Qi Shi, Zheng-Wen Fu
Format: Article
Language:English
Published: Nature Publishing Group 2017-09-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-017-00677-3