Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide
The rational design of intercalation electrodes is largely confined to the optimization of redox chemistry of transition metals and oxygen. Here, the authors report the single anionic redox process in NaCrS2 where it is sulfur rather than chromium that works as the electrochemical active species.
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| Format: | Article |
| Language: | English |
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Nature Publishing Group
2017-09-01
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| Series: | Nature Communications |
| Online Access: | https://doi.org/10.1038/s41467-017-00677-3 |
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doaj-78e167c88fe04ef5a9ff292c7e4bd449 |
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Article |
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doaj-78e167c88fe04ef5a9ff292c7e4bd4492021-05-11T07:42:14ZengNature Publishing GroupNature Communications2041-17232017-09-01811910.1038/s41467-017-00677-3Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfideZulipiya Shadike0Yong-Ning Zhou1Lan-Li Chen2Qu Wu3Ji-Li Yue4Nian Zhang5Xiao-Qing Yang6Lin Gu7Xiao-Song Liu8Si-Qi Shi9Zheng-Wen Fu10Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry & Laser Chemistry Institute, Fudan UniversityDepartment of Material Science, Fudan UniversitySchool of Materials Science and Engineering, Shanghai UniversitySchool of Materials Science and Engineering, Shanghai UniversityShanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry & Laser Chemistry Institute, Fudan UniversityState Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of ScienceDepartment of Material Science, Fudan UniversityBeijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of SciencesState Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of ScienceSchool of Materials Science and Engineering, Shanghai UniversityShanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Department of Chemistry & Laser Chemistry Institute, Fudan UniversityThe rational design of intercalation electrodes is largely confined to the optimization of redox chemistry of transition metals and oxygen. Here, the authors report the single anionic redox process in NaCrS2 where it is sulfur rather than chromium that works as the electrochemical active species.https://doi.org/10.1038/s41467-017-00677-3 |
| collection |
DOAJ |
| language |
English |
| format |
Article |
| sources |
DOAJ |
| author |
Zulipiya Shadike Yong-Ning Zhou Lan-Li Chen Qu Wu Ji-Li Yue Nian Zhang Xiao-Qing Yang Lin Gu Xiao-Song Liu Si-Qi Shi Zheng-Wen Fu |
| spellingShingle |
Zulipiya Shadike Yong-Ning Zhou Lan-Li Chen Qu Wu Ji-Li Yue Nian Zhang Xiao-Qing Yang Lin Gu Xiao-Song Liu Si-Qi Shi Zheng-Wen Fu Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide Nature Communications |
| author_facet |
Zulipiya Shadike Yong-Ning Zhou Lan-Li Chen Qu Wu Ji-Li Yue Nian Zhang Xiao-Qing Yang Lin Gu Xiao-Song Liu Si-Qi Shi Zheng-Wen Fu |
| author_sort |
Zulipiya Shadike |
| title |
Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide |
| title_short |
Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide |
| title_full |
Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide |
| title_fullStr |
Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide |
| title_full_unstemmed |
Antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide |
| title_sort |
antisite occupation induced single anionic redox chemistry and structural stabilization of layered sodium chromium sulfide |
| publisher |
Nature Publishing Group |
| series |
Nature Communications |
| issn |
2041-1723 |
| publishDate |
2017-09-01 |
| description |
The rational design of intercalation electrodes is largely confined to the optimization of redox chemistry of transition metals and oxygen. Here, the authors report the single anionic redox process in NaCrS2 where it is sulfur rather than chromium that works as the electrochemical active species. |
| url |
https://doi.org/10.1038/s41467-017-00677-3 |
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1721451773134110720 |