A new approach to alkaloid-like systems: synthesis and crystal structure of 1-(2-acetyl-11-methoxy-5,6-dihydro[1,3]dioxolo[4,5-g]pyrrolo[2,1-a]isoquinolin-1-yl)propan-2-one

A new approach to alkaloid-like systems: synthesis and crystal structure of 1-(2-acetyl-11-methoxy-5,6-dihydro[1,3]dioxolo[4,5-g]pyrrolo[2,1-a]isoquinolin-1-yl)propan-2-one

The title compound, C19H19NO5, (I), is the product of a domino reaction between cotarnine chloride and acetylacetylene catalysed by copper(I) iodide. The molecule of (I) comprises a fused tetracyclic system containing two terminal five-membered rings (pyrrole and 1,3-dioxole) and two central six-mem...

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Bibliographic Details
Main Authors: Le Tuan Anh, Alexander A. Titov, Reza Samavati, Leonid G. Voskressensky, Alexey V. Varlamov, Victor N. Khrustalev
Format: Article
Language:English
Published: International Union of Crystallography 2017-11-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
alkaloids
lamellarin
cotarnine
dihydropyrrolo[2,1-a]isoquinolines
domino reaction
crystal structure
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989017015110

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http://scripts.iucr.org/cgi-bin/paper?S2056989017015110

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