Crystal structure of (±)-[trans-cyclohexane-1,2-diylbis(azanediyl)]diphosphonium dibromide dichloromethane disolvate

Crystal structure of (±)-[trans-cyclohexane-1,2-diylbis(azanediyl)]diphosphonium dibromide dichloromethane disolvate

The cation of the title solvated salt, C42H42N2P22+·2Br−·2CH2Cl2, lies on a crystallographic twofold rotation axis. The 1,2-diaminocyclohexane fragment has a chair conformation with two N atoms in a transoid conformation [N—C—C—N = 163.4 (2)°]. In the crystal, the cations are linked to the anions by...

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Bibliographic Details
Main Authors: Aurora Rodríguez Álvarez, Hugo Tlahuext, Jean-Michel Grévy
Format: Article
Language:English
Published: International Union of Crystallography 2016-04-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
trans-diaminocyclohexane
diphosphonium ligands
C—H...Br and C—H...π interactions
Online Access:http://scripts.iucr.org/cgi-bin/paper?S2056989016004576

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http://scripts.iucr.org/cgi-bin/paper?S2056989016004576

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