New Phosphorous-Based [FeFe]-Hydrogenase Models

New Phosphorous-Based [FeFe]-Hydrogenase Models

[FeFe]-hydrogenases have attracted research for more than twenty years as paragons for the design of new catalysts for the hydrogen evolution reaction (HER). The bridging dithiolate comprising a secondary amine as bridgehead is the key element for the reactivity of native [FeFe]-hydrogenases and was...

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Bibliographic Details
Main Authors: Florian Wittkamp, Esma Birsen Boydas, Michael Roemelt, Ulf-Peter Apfel
Format: Article
Language:English
Published: MDPI AG 2020-05-01
Series:Catalysts
Subjects:
[FeFe]-hydrogenase mimic
element homologue replacement
reduction of phosphinates and phosphines
cyclic voltammetry
Mössbauer spectroscopy
infrared spectroscopy
Online Access:https://www.mdpi.com/2073-4344/10/5/522

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https://www.mdpi.com/2073-4344/10/5/522

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