Synergetic effect of multi-site phase transfer catalysis system mediated free radical polymerization of acrylonitrile – a kinetic study

In this work, the kinetics and mechanism of free radical polymerization of acrylonitrile (AN) using potassium peroxydisulphate (PDS-K2S2O8) as a water soluble initiator in the presence of synthesized 4,4'-dihexadecyl-1,1'-bipyridine diiumdichloride (DHBPDDC) as multi-site phase-transfer ca...

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Bibliographic Details
Main Authors: Manickam Sathiyaraj, Perumal Venkatesh, Venugopal Rajendran
Format: Article
Language:English
Published: Iranian Chemical Science and Technologies Association 2019-02-01
Series:Chemical Review and Letters
Subjects:
Online Access:http://www.chemrevlett.com/article_88617_d7065bb8a380ce969e3ca779f4fb39fc.pdf