Visible light-mediated difluoroalkylation of electron-deficient alkenes

Visible light-mediated difluoroalkylation of electron-deficient alkenes

A method for the reductive difluoroalkylation of electron-deficient alkenes using 1,1-difluorinated iodides mediated by irradiation with blue light is described. The reaction involves radical addition of 1,1-difluorinated radicals at the double bond followed by hydrogen atom transfer from sodium cya...

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Bibliographic Details
Main Authors: Vyacheslav I. Supranovich, Vitalij V. Levin, Marina I. Struchkova, Jinbo Hu, Alexander D. Dilman
Format: Article
Language:English
Published: Beilstein-Institut 2018-07-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
difluoroalkylation
organofluorine compounds
radical addition
visible light
Online Access:https://doi.org/10.3762/bjoc.14.139

Internet

https://doi.org/10.3762/bjoc.14.139

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