Superelectrophilic activation of 5-hydroxymethylfurfural and 2,5-diformylfuran: organic synthesis based on biomass-derived products

Superelectrophilic activation of 5-hydroxymethylfurfural and 2,5-diformylfuran: organic synthesis based on biomass-derived products

The reaction of 5-hydroxymethylfurfural (5-HMF) with arenes in superacidic trifluoromethanesulfonic acid (triflic acid, TfOH) as the solvent at room temperature for 1–24 h gives rise to 5-arylmethylfurfurals (yields of 17–91%) and 2-arylmethyl-5-(diarylmethyl)furans (yields of 10–37%). The formation...

Full description

Bibliographic Details
Main Authors: Dmitry S. Ryabukhin, Dmitry N. Zakusilo, Mikhail O. Kompanets, Anton A.Tarakanov, Irina A. Boyarskaya, Tatiana O. Artamonova, Mikhail A. Khohodorkovskiy, Iosyp O. Opeida, Aleksander V. Vasilyev
Format: Article
Language:English
Published: Beilstein-Institut 2016-10-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
2,5-diformylfuran
Friedel–Crafts reaction
5-hydroxymethylfurfural
superacids
zeolites
Online Access:https://doi.org/10.3762/bjoc.12.202

Internet

https://doi.org/10.3762/bjoc.12.202

Similar Items