Aerobic Epoxidation of Low-Molecular-Weight and Polymeric Olefins by a Supramolecular Manganese Porphyrin Catalyst

We report on the highly efficient epoxidation of low-molecular-weight and polymeric olefins catalyzed by a supramolecular manganese porphyrin complex using molecular oxygen as an oxidant and an aldehyde as a co-reductant. At ambient temperature and under optimized reaction conditions, the catalyst s...

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Bibliographic Details
Main Authors: Ivan Bernar, Floris P.J.T. Rutjes, Johannes A.A.W. Elemans, Roeland J.M. Nolte
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:Catalysts
Subjects:
Online Access:https://www.mdpi.com/2073-4344/9/2/195