Palanquin-Like Cu<sub>4</sub>Na<sub>4</sub> Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides

Palanquin-Like Cu<sub>4</sub>Na<sub>4</sub> Silsesquioxane Synthesis (via Oxidation of 1,1-bis(Diphenylphosphino)methane), Structure and Catalytic Activity in Alkane or Alcohol Oxidation with Peroxides

The self-assembly synthesis of copper-sodium phenylsilsesquioxane in the presence of 1,1-bis(diphenylphosphino)methane (dppm) results in an unprecedented cage-like product: [(PhSiO<sub>1,5</sub>)<sub>6</sub>]<sub>2</sub>[CuO]<sub>4</sub>[NaO<sub>...

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Bibliographic Details
Main Authors: Alena N. Kulakova, Victor N. Khrustalev, Yan V. Zubavichus, Lidia S. Shul’pina, Elena S. Shubina, Mikhail M. Levitsky, Nikolay S. Ikonnikov, Alexey N. Bilyachenko, Yuriy N. Kozlov, Georgiy B. Shul'pin
Format: Article
Language:English
Published: MDPI AG 2019-02-01
Series:Catalysts
Subjects:
alkanes
hydrogen peroxide
copper complexes
metallasilsesquioxanes
dppm oxidation
Online Access:https://www.mdpi.com/2073-4344/9/2/154

Internet

https://www.mdpi.com/2073-4344/9/2/154

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