Self-assembly of a helical zinc-europium complex: speciation in aqueous solution and luminescence

Self-assembly of a helical zinc-europium complex: speciation in aqueous solution and luminescence

Two new tridentate(NNO)-bidentate(NN) compartmental ligands, HL5 and HL6, are synthesized from pyridine and benzimidazole synthons. They react in aqueous solution under physiological conditions with ZnII, LnIII, or a mixture thereof, to yield complexes of different stoichiometries, 1:3, 2:2, 2:3, 1:...

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Bibliographic Details
Main Authors: Emmanuel eDeiters, Svetlana Valerevna Eliseeva, Jean-Claude Georges Bünzli
Format: Article
Language:English
Published: Frontiers Media S.A. 2013-09-01
Series:Frontiers in Chemistry
Subjects:
lanthanides
stability constants determination
bimetallic
dinuclear
helicate
photophysical properties
Online Access:http://journal.frontiersin.org/Journal/10.3389/fchem.2013.00015/full

Internet

http://journal.frontiersin.org/Journal/10.3389/fchem.2013.00015/full

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