S–H Bond Activation in Hydrogen Sulfide by NHC-Stabilized Silyliumylidene Ions

S–H Bond Activation in Hydrogen Sulfide by NHC-Stabilized Silyliumylidene Ions

Reactivity studies of silyliumylidenes remain scarce with only a handful of publications to date. Herein we report the activation of S–H bonds in hydrogen sulfide by mTer-silyliumylidene ion A (mTer = 2,6-Mes2-C6H3, Mes = 2,4,6-Me3-C6H2) to yield an NHC-stabilized thiosilaaldehyde B. The r...

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Bibliographic Details
Main Authors: Amelie Porzelt, Julia I. Schweizer, Ramona Baierl, Philipp J. Altmann, Max C. Holthausen, Shigeyoshi Inoue
Format: Article
Language:English
Published: MDPI AG 2018-05-01
Series:Inorganics
Subjects:
silicon
N-heterocyclic carbenes
silyliumylidenes
small molecule activation
mechanistic insights
Online Access:http://www.mdpi.com/2304-6740/6/2/54

Internet

http://www.mdpi.com/2304-6740/6/2/54

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