Enantiopure Radical Cation Salt Based on Tetramethyl-Bis(ethylenedithio)-Tetrathiafulvalene and Hexanuclear Rhenium Cluster

Enantiopure Radical Cation Salt Based on Tetramethyl-Bis(ethylenedithio)-Tetrathiafulvalene and Hexanuclear Rhenium Cluster

Electrocrystallization of the (S,S,S,S) enantiomer of tetramethyl-bis(ethylenedithio)-tetrathiafulvalene donor 1 in the presence of the dianionic hexanuclear rhenium (III) cluster [Re6S6Cl8]2− affords a crystalline radical cation salt formulated as [(S)-1]2·Re6S6Cl8, in which the methyl substituents...

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Bibliographic Details
Main Authors: Flavia Pop, Patrick Batail, Narcis Avarvari
Format: Article
Language:English
Published: MDPI AG 2016-01-01
Series:Crystals
Subjects:
chirality
crystal structure
tetrathiafulvalenes
rhenium clusters
Online Access:http://www.mdpi.com/2073-4352/6/1/8

Internet

http://www.mdpi.com/2073-4352/6/1/8

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