Serendipitous preparation of fac-(acetonitrile-κN)trichlorido[(1,2,5,6-η)-cycloocta-1,5-diene]iridium(III)
A reaction between [(COD)IrCl]2 (COD is cycloocta-1,5-diene), HCl and indene failed to provide the hoped for chloridoindenyliridium dimer, but instead produced the title compound, [IrCl3(CH3CN)(C8H12)], which is an octahedral complex of iridium(III) with a chelating cycloocta-1,5-diene ligand, three...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2015-04-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989015004855 |